Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination
نویسندگان
چکیده
(PyH)2[MoOCl5] was obtained in the form of emerald green crystals unintentionally from (PyH)5[MoOCl4(H2O)]3Cl2 acetonitrile. has been used as a starting material molybdenum(V) coordination chemistry for decades, yet its true identity not known until now. The X-ray structure analysis undoubtedly confirmed existence this compound. [MoOCl5]2− ion displays usual structural characteristics mononuclear MoO3+-containing compounds.
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ژورنال
عنوان ژورنال: Molbank
سال: 2021
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1249